Instrumental Techniques for Analytical Chemistry

Introduction Infrared (IR) spectroscopy is one of the most common spectroscopic techniques used by organic and inorganic chemists. Simply, it is the absorption measurement of different IR frequencies by a sample positioned in the path of an IR beam. The main goal of IR spectroscopic analysis is to determine the chemical functional groups in the sample. Different functional groups absorb characteristic frequencies of IR radiation. Using various sampling accessories, IR spectrometers can accept a wide range of sample types such as gases, liquids, and solids. Thus, IR spectroscopy is an important and popular tool for structural elucidation and compound identification. IR Frequency Range and Spectrum Presentation Infrared radiation spans a section...

INTERPRETING AN INFRA-RED SPECTRUM

This page explains how to use an infra-red spectrum to identify the presence of a few simple bonds in organic compounds.   The infra-red spectrum for a simple carboxylic acid Ethanoic acid Ethanoic acid has the structure: You will see that it contains the following bonds: carbon-oxygen double, C=O carbon-oxygen single, C-O oxygen-hydrogen, O-H carbon-hydrogen, C-H carbon-carbon single, C-CThe carbon-carbon bond has absorptions which occur over a wide range of wavenumbers in the fingerprint region - that makes it very difficult to pick out on an infra-red spectrum. The carbon-oxygen single bond also has an absorbtion in the fingerprint region, varying between 1000 and 1300 cm-1 depending on the molecule it is in. You have...

Infra Red Waves

Infrared light lies between the visible and microwave portions of the electromagnetic spectrum. Infrared light has a range of wavelengths, just like visible light has wavelengths that range from red light to violet. "Near infrared" light is closest in wavelength to visible light and "far infrared" is closer to the microwave region of the electromagnetic spectrum. The longer, far infrared wavelengths are about the size of a pin head and the shorter, near infrared ones are the size of cells, or are microscopic. Far infrared waves are thermal. In other words, we experience this type of infrared radiation every day in the form of heat! The heat that we feel from sunlight, a fire, a radiator or a warm sidewalk is infrared. The...

What does the Infrared show us?

This is an infrared image of the Earth taken by the GOES 6 satellite in 1986. A scientist used temperatures to determine which parts of the image were from clouds and which were land and sea. Based on these temperature differences, he colored each separately using 256 colors, giving the image a realistic appearance. Why use the infrared to image the Earth? While it is easier to distinguish clouds from land in the visible range, there is more detail in the clouds in the infrared. This is great for studying cloud structure. For instance, note that darker clouds are warmer, while lighter clouds are cooler. Southeast of the Galapagos, just west of the coast of South America, there is a place where you can distinctly...

What is it?

The electromagnetic spectrum is more familiar to you than you might think. The microwave you use to heat your food and the cell phones you use are part of the Electromagnetic Spectrum. The light that our eyes can see is also part of the electromagnetic spectrum. This visible part of the electromagnetic spectrum consists of the colors that we see in a rainbow - from reds and oranges, through blues and purples. Each of these colors actually corresponds to a different wavelength of light Waves in the electromagnetic spectrum vary in size from very long radio waves the size of buildings, to very short gamma-rays smaller than the size of the...

Infrared Spectroscopy II

Infrared spectroscopy is spectroscopy in the infrared (IR) region of the electromagnetic spectrum. It is a vital part of infrared astronomy, just as it is in visual, or optical, astronomy (and has been since lines were discovered in the spectrum of the Sun, in 1802, though it was a couple of decades before Fraunhofer began to study them systematically). For the most part, the techniques used in IR spectroscopy, in astronomy, are the same or very similar to those used in the visual waveband; confusingly, then, IR spectroscopy is part of both infrared astronomy and optical astronomy! These techniques involve use of mirrors, lenses, dispersive media such as prisms or gratings, and ‘quantum’ detectors (silicon-based CCDs in the...